Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

美国出口管制下中国外贸风险的省域地理差异     

姜辉 《地理科学》2020,40(10):1618-1626

从总贸易、出口、进口、外资和人员5个视角构建对美风险系数，测度和比较各省区市对美外贸风险的地理差异。结果表明：上海、浙江和福建与美国的进出口贸易规模最大，对美国市场的依赖程度最高，面临的综合外贸风险最大；河南尤其需要防范对美国的出口风险；海南、新疆、天津和西藏等需要加强从美国进口的风险管理；重庆除了需要防范对美出口风险外，还因为实际利用美资最多且依赖程度最大，亟需加强外资风险管理。宁夏和山西虽然从美国的引资规模不大，但是对美资的依赖程度最高，亟需提升外资多元化水平。从人员跨境流动风险来看，上海、北京和浙江面临的风险最大。中国各省区市在应对美国出口管制时应该加强外贸风险的识别和管理，针对不同的风险采取差别化的防范和化解措施。  相似文献   

乡土地理实践活动案例分析与应用——以“明光市女山古火山地质公园考察”为例     

孙玉林  陈荟 《地理教学》2020,(2):30-32

地理实践是地理科学的重要研究方法,也是中学地理学科的主要学习方式之一。中学地理实践活动应结合乡土地理资源,充分挖掘当地可供考察的自然、人文素材,形成丰富的乡土地理实践案例。本文以“女山古火山地质公园实践活动为案例”,探究乡土资源在地理实践活动中的应用。  相似文献   

河南省现代服务业集聚特征及影响因素分析     

孟琳琳  李江苏  李明月  宋莹莹 《世界地理研究》2020,29(6):1202-1212

现代服务业是伴随着科技发展而出现的一种新兴产业，对区域产业结构优化升级、促进经济发展等方面日趋重要。采用空间基尼系数、区位熵分析、EG指数和面板回归等方法，对2007—2017年河南省现代服务业集聚特征及影响因素进行分析，得出以下结论：①河南省现代服务业总体及其8个分行业集聚程度较高，其中科学研究和技术服务业集聚程度最高，教育最低；②河南省现代服务业总体及其8个分行业专业化水平较低，其中郑州市专业化水平最高，并在金融业，文化、体育和娱乐业2个行业表现出较强的集聚优势；③河南省现代服务业总体及其8个分行业空间集聚结构较差，发展还不成熟；④经济发展水平对河南省现代服务业发展影响最大，交通条件、资本支持、信息化水平和人力资本对现代服务业发展具有不同程度的促进作用，工业化水平、政府行为对其产生显著的负影响。  相似文献   

“一带一路”背景下的中国与巴基斯坦的贸易关系演进及其影响因素     

宋周莺  祝巧玲 《地理科学进展》2020,39(11):1785-1797

中巴经济走廊是“一带一路”6大经济走廊之一,而贸易畅通是“一带一路”建设的核心环节。研究中巴贸易关系演变及其影响因素、分析其贸易潜力,对推进“一带一路”建设具有重要的示范作用。论文从中巴贸易发展态势、商品结构、空间格局等方面揭示中巴贸易关系,运用随机前沿引力模型分析中巴贸易关系的主要影响因素、并探析其发展潜力,以期为推进中巴经济走廊建设提供科学支撑。研究发现：① 中巴贸易发展迅速,中对巴贸易顺差持续扩大;中国主要出口机械及电气设备等资本密集型产品,主要进口纺织原料及纺织制品等初级产品和劳动密集型产品。② 中国各省份与巴基斯坦的贸易合作存在明显的空间差异,东部沿海省份与巴贸易联系较紧密,西部各省份除新疆外与巴基斯坦贸易额均较小。③ 中国多数省份对巴贸易商品结构发生显著变动,其中,新疆、山东等进出口商品结构多元的省份的变动相对较小。④ 中国各省份的经济发展水平和市场规模对中巴贸易拉动较强;海运距离对中巴贸易规模有显著的负向影响;领土接壤为中巴组织边境贸易提供了良好条件;铁路和水运口岸的建设对中巴贸易具有积极影响。⑤ 中国各省份与巴基斯坦均有较大贸易潜力,内蒙古、云南、广西、陕西等省份的合作潜力更明显。  相似文献   

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析          下载免费PDF全文

武翠玲  宋英达  高慧芳  张廉芸  任晨霞 《盐湖研究》2020,28(1)

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献   

Fe₃O₄/Mg(OH)₂复合材料的制备及形貌控制          下载免费PDF全文

韩文生  李丽娟  宋富根  时东  张禹泽  李娜  郭凡 《盐湖研究》2020,28(3):93-98

通过种子沉积法制备出Fe_3O_4/Mg(OH)_2复合材料并进行XRD、SEM测试分析。探究了氨水的浓度与加入速度、搅拌速度及等因素对磁性复合材料形貌的影响。氨水浓度与注入速度的降低,对氢氧化镁基体形貌的影响是相同的,但要使合成磁性复合材料形貌和四氧化三铁粒子在氢氧化镁中分散性均匀,应控制氨水浓度(ω=2.5%)或加入速度在一个合理的较低值。  相似文献   

Identifying primary public transit corridors using multi-source big transit data     

Tong Zhang  Yicong Li  Hui Yang  Chenrong Cui  Jing Li  Qinghua Qiao 《International journal of geographical information science》2020,34(6):1137-1161

ABSTRACT

Effective public transit planning needs to address realistic travel demands, which can be illustrated by corridors across major residential areas and activity centers. It is vital to identify public transit corridors that contain the most significant transit travel demand patterns. We propose a two-stage approach to discover primary public transit corridors at high spatio-temporal resolutions using massive real-world smart card and bus trajectory data, which manifest rich transit demand patterns over space and time. The first stage was to reconstruct chained trips for individual passengers using multi-source massive public transit data. In the second stage, a shared-flow clustering algorithm was developed to identify public transit corridors based on reconstructed individual transit trips. The proposed approach was evaluated using transit data collected in Shenzhen, China. Experimental results demonstrated that the proposed approach is a practical tool for extracting time-varying corridors for many potential applications, such as transit planning and management.  相似文献   

A case study on Landscape Component Niche based on Landscape Pattern Indices: Yanchi,Ningxia Province,China     

XiaoNing Zhang  XueLu Liu  Ghanney Philip  XiaoDan Li  QuanXi Wang  YaNan Xu  TingTing Hui 《寒旱区科学》2020,(1):22-33

Yanchi County is located in the agro-pastoral ecotone and belongs to the ecologically fragile area of Northwest China.It is important to study the evolution of landscape pattern to curb its environmental degradation.In order to intuitively show how the landscape pattern of the study area changes over time,Landsat Thematic Mappers(TM)and Landsat Operational Land Imager(OLI)data of 1991,2000,2010 and 2017 were used.This paper attempts to apply niche theories and methods into landscape ecology,and constructs a niche model of landscape components by using"n-dimentional hypervolume niche theory"and landscape pattern indices.By evaluating the spatial and temporal evolution of niche from the perspective of two-dimensional space to reflect the changes of landscape pattern in the study area over the past 26 years,new theories and methods were introduced for the characterization of landscape pattern.The results indicate that:1)The larger the attribute and dominance value of landscape components,the higher the ecological niche and the stronger the control effect on the overall landscape.2)The ecological niche of each landscape component was significantly different,just as its control effect on the overall landscape.3)The dynamic change of the ecological niche of each landscape component was different,with grassland,unused land and arable land always in a high dominant position,although the ecological niche of construction land and water area was always low.In general,the introduction of niche theory into the landscape ecology provided a new method to study the changes in regional landscape pattern.  相似文献   

Structural strength deterioration of coastal bridge piers considering non-uniform corrosion in marine environments     

Anxin Guo  Wenting Yuan  Haitao Li  Hui Li 《地震工程与工程振动(英文版)》2018,17(2):429-444

In the aggressive marine environment over a long-term service period,coastal bridges inevitably sustain corrosion-induced damage due to high sea salt and humidity.This paper investigates the strength reduction of coastal bridges,especially focusing on the effects of non-uniform corrosion along the height of bridge piers.First,the corrosion initiation time and the degradation of reinforcement and concrete are analyzed for bridge piers in marine environments.To investigate the various damage modes of the concrete cover,a discretization method with fiber cells is used for calculating time-dependent interaction diagrams of cross-sections of the bridge piers at the atmospheric zone and the splash and tidal zone under a combination of axial force and bending moment.Second,the shear strength of these aging structures is analyzed.Numerical simulation indicates that the strength of a concrete pier experiences dramatic reduction from corrosion initiation to the spalling of the concrete cover.Strength loss in the splash and tidal zone is more significant than in the atmospheric zone when structures’service time is assumed to be the same.  相似文献